P-Block Elements MCQs With Answers For Class 12 Chemistry JEE NEET

The p-Block Elements MCQs with Answers

Practicing MCQs on p-block elements with provided answers is highly beneficial for NEET/JEE preparation. This approach offers immediate feedback, which helps you identify and correct mistakes promptly. The detailed explanations that accompany the answers clarify complex topics and strengthen your understanding. 

Regularly working with MCQs that include answers not only improves your knowledge of p-block elements but also boosts your confidence and problem-solving abilities. This method ensures thorough preparation, making it easier for you to tackle similar questions in the NEET/JEE exams with greater accuracy.

By consistently applying these strategies and practicing MCQs, you will significantly improve your understanding of p-block elements and enhance your overall performance in NEET/JEE exmas and score high in class 12 board exam.

Q 1. A single N-N bond is weaker than a single P-P bond. This is because of;

(1) larger N-N bond length in comparison to P-P bond length.

(2) high interelectronic repulsion of the non-bonding electrons, owing to the small N-N bond length in comparison to that in the P-P single bond.

(3) higher electronegativity of N in comparison to P.

(4) smaller atomic size of N as compared to that of P.

Ans. 2

Q 2. Which one of the following does not show allotropy?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Antimony

Ans. 1

Q 3. Which of the following group 15 elements forms metallic bonds in an elemental state?

(1) As 

(2) P

(3) Sb 

(4) Bi

Ans. 4

Q 4. Metalloids in the carbon and nitrogen families are;

(1) Si, As 

(2) P, Sn

(3) Pb, Sb 

(4) C, Bi

Ans. 1

Q 5. Assertion (A): N2 is less reactive than P4.

Reason (R): Nitrogen has more electron gain enthalpy than phosphorous.

(1) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).

(2) Both Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A).

(3) Assertion (A) is true and Reason (R) is false.

(4) Assertion (A) is false and Reason (R) is true.

Ans. 3

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Q 6. Maximum covalency of nitrogen is;

(1) 3 

(2) 4

(3) 5 

(4) 6

Ans. 2

Q 7. The correct statement about phosphorus atom is;

(1) It has 5 vacant orbitals in the valence shell.

(2) It has 3 unpaired electrons.

(3) Nine electrons have similar spin.

(4) All of these

Ans. 4

Q 8. Which is true regarding nitrogen? (C.E.T.)

(1) Less electronegative.

(2) Has low ionisation enthalpy.

(3) d-orbitals are available.

(4) Ability to form pπ-pπ bonds with itself.

Ans. 4

Q 9. p-block elements are those elements in which the last electron enters in;

(1) p-orbital 

(2) s-orbital

(3) d-orbital 

(4) None of these

Ans. 1

Q 10. Nitrogen doesn’t form pentahalide due to non-availability of;

(1) s orbital 

(2) p orbital

(3) d orbital 

(4) None of these

Ans. 3

Q 11. What causes dinitrogen to be chemically inert?

(1) Multiple bond formation in the molecule.

(2) Presence of bond polarity.

(3) Large internuclear distance.

(4) Low bond energy.

Ans. 1

Q 12. The tendency to exhibit -3 oxidation state ______ down the group.

(1) decreases 

(2) increases

(3) remains same 

(4) None of these

Ans. 1

Q 13. Which elements of group 15 are metalloids?

(1) P 

(2) N

(3) Sb 

(4) Bi

Ans. 3

Q 14. Which of the following statements is not true for phosphorus?

(1) Phosphorus is a non-metal.

(2) It exists as a tetrahedral molecular solid.

(3) Phosphorus is less reactive than nitrogen.

(4) The P-P bond is much weaker than the N ≡ N bond.

Ans. 3

Q 15. Statement-I: Phosphorus has a higher melting point due to its larger size than nitrogen.

Statement II: Nitrogen is inert due to the formation of triple bonds and has a lower covalence due to the non-availability of d-orbitals.

(1) Statement-I and Statement-II both are correct.

(2) Statement I is correct but Statement II is incorrect.

(3) Statement I is incorrect but Statement II is correct.

(4) Statement-I and Statement-II both are incorrect.

Ans. 1

Q 16. Atomic radii of group 15 elements are of the order;

(1) N > P > As > Bi > Sb

(2) N > P > As > Sb > Bi

(3) N < P < As < Sb < Bi

(4) N < P < As < Sb > Bi

Ans. 3

Q 17. In group 15, the melting points of the elements;

(1) increase regularly on moving down the group.

(2) decrease regularly on moving down the group.

(3) First decrease up to As and then increase to Bi.

(4) first increase from N to As and then decrease to Bi.

Ans. 4

Q 18. Which of the following does show maximum allotropy?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Antimony

Ans. 2

Q 19. The metallic character among the Group 15 elements increases down the group due to;

(1) increase in ionization energy.

(2) increase in atomic size.

(3) increase in electronegativity.

(4) None of these

Ans. 2

Q 20. The atomicity of nitrogen and phosphorus is respectively.

(1) 2 and 2 

(2) 2 and 3

(3) 2 and 4 

(4) 2 and 5

Ans. 3

Q 21. Which of the following elements in Group 15 exhibits the highest melting point?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 3

Q 22. Which of the following Group 15 elements exists in the gaseous phase at room temperature and pressure?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Antimony

Ans. 1

Q 23. The boiling point of phosphorus is higher than that of nitrogen due to;

(1) Greater atomic radius of phosphorus.

(2) Presence of stronger London dispersion forces in phosphorus.

(3) Higher electronegativity of phosphorus.

(4) Presence of d-orbitals in phosphorus.

Ans. 2

Q 24. Which of the following Group 15 elements has the highest atomic radius?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 4

Q 25. Which Group 15 element has the highest first ionization energy?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 1

Q 26. Among the Group 15 elements, which one has the highest electronegativity value?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 1

Q 27. The element in Group 15 with the lowest melting point is;

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 1

Q 28. What is the oxidation state of nitrogen in dinitrogen trioxide?

(1) +1 

(2) +2

(3) +3 

(4) +4

Ans. 3

Q 29. What is the range of the oxidation states shown by nitrogen in its oxides?

(1) +1 to +3 

(2) +2 to +4

(3) +1 to +2 

(4) +1 to +5

Ans. 4

Q 30. The three important oxidation states of phosphorus are;

(1) –3, +3 and +5

(2) –3, +3 and –5

(3) –3, +3 and +2

(4) –3, +3 and +4

Ans. 1

Q 31. The oxidation state of phosphorus varies from;

(1) –1 to +3 

(2) –3 to +3

(3) –3 to +5 

(4) –5 to +1

Ans. 3

Q 32. Among the Group 15 elements, which of the following has the least tendency to show the inert pair effect?

(1) Nitrogen 

(2) Phosphorus

(3) Arsenic 

(4) Bismuth

Ans. 1

Q 33. Nitrogen shows anomalous behaviour in its oxidation states because of;

(1) Its small atomic size.

(2) Its ability to form multiple bonds.

(3) Its higher electronegativity.

(4) All of these

Ans. 4

Q 34. Which of the following statements are not correct about the hydrides of group 15 elements;

(1) The hydrides of the elements of group 15 are ionic and have a planar triangular shape

(2) The thermal stability of the hydrides decreases down the group

(3) The basic character of the hydrides decreases down the group

(4) The reducing nature of the hydrides increases down the group

Ans. 1

Q 35. The trend in the hydrides from Bi to N is;

(1) bond length increases

(2) bond length decreases

(3) acidic nature increases

(4) bond energy decreases

Ans. 2

Q 36. The incorrect statement among the following is;

(1) Reducing the character of hydrides of group 15 increases down the group.

(2) The basicity of hydrides of group 15 increases down the group.

(3) Phosphorus and arsenic can form pπ-dπ bonds but not nitrogen.

(4) None of these

Ans. 2

Q 37. Which of the following is correct about VA group hydrides (from ammonia to bismuth)?

(1) Their thermal stability gradually increases.

(2) Their ease of preparation gradually increases.

(3) The electron pair donating nature gradually decreases.

(4) The bond energies gradually increase.

Ans. 3

Q 38. Among the hydrides of the 15th group, which is a strong reducing agent?

(1) Ammonia 

(2) Phosphine

(3) Arsine 

(4) Bismuthine

Ans. 4

Q 39. The number of oxides that are possible with nitrogen is;

(1) 4 

(2) 3

(3) 6 

(4) 5

Ans. 4

Q 40. Ammonia is liquid and phosphene is gas. Why?

(1) Due to more molar mass ammonia has maximum vanderwall force of attraction.

(2) Due to more molar mass ammonia has less Vanderwall force of attraction.

(3) Due to the presence of intermolecular hydrogen bonding in ammonia.

(4) Due to the absence of hydrogen bonding in ammonia.

Ans. 3

Q 41. Which of the following oxide can act as both a reducing and oxidising agent?

(1) Dinitrogen oxide 

(2) Nitric oxide

(3) Dinitrogen pentoxide 

(4) None of these

Ans. 2

Q 42. Ammonia is a Lewis base and acts as a complexing agent because;

(1) It accepts electron pairs.

(2) It is neither an electron pair donor nor an acceptor.

(3) It acts as an electron pair donor.

(4) It exhibits a covalency of more than five.

Ans. 3

Q 43. Which of the following is the correct order of melting points of group 16 elements?

(1) O < S < Se < Te < Po

(2) O < Se < S < Te < Po

(3) O < S < Se < Te > Po

(4) O < S < Se > Te < Po

Ans. 3

Q 44. Which of the following elements does not belong to group 16 of the periodic table?

(1) Oxygen 

(2) Phosphorus

(3) Sulphur 

(4) Selenium

Ans. 2

Q 45. Arrange the following elements in order of their increasing ionisation energies O, S, Se, Te, Po;

(1) Po, Te, Se, S, O 

(2) Se, Te, S, Po, O

(3) Te, O, S, Po, Se 

(4) O, S, Se, Te, Po

Ans. 1

Q 46. Which of the following is a true chalcogen?

(1) Nitrogen 

(2) Oxygen

(3) Polonium 

(4) Chlorine

Ans. 2

Q 47. The electron affinity of sulphur is;

(1) less than O but more than Se.

(2) more than O but less than Se.

(3) more than O and Se.

(4) equal to O and Se.

Ans. 1

Q 48. Which of the following is the correct order of electron gain enthalpy of group 16 elements?

(1) O > S > Se > Te > Po

(2) S > O > Se > Te > Po

(3) S > Se > Te > Po > O

(4) S > Se > O > Te > Po

Ans. 3

Q 49. A group of 16 elements exists in a monoatomic state in the metallic lattice. It also exists in two crystalline forms. The metal is;

(1) S 

(2) Te

(3) Po 

(4) Se

Ans. 3

Q 50. Which shows maximum catenation property?

(1) Te 

(2) S

(3) Se 

(4) O

Ans. 2

Q 51. Which of the following is radioactive in nature?

(1) Oxygen 

(2) Sulphur

(3) Tellurium 

(4) Polonium

Ans. 4

Q 52. The chalcogen with the lowest electron affinity is;

(1) Oxygen 

(2) Sulphur

(3) Selenium 

(4) Tellurium

Ans. 1

Q 53. Which group 16 element has the highest tendency for catenation?

(1) Oxygen 

(2) Sulphur

(3) Selenium 

(4) Polonium

Ans. 2

Q 54. Among the group 16 elements the only element that does not exist as an octa-atomic solid is;

(1) Sulphur 

(2) Selenium

(3) Oxygen 

(4) Tellurium

Ans. 3

Q 55. Catenation is maximum in sulphur upto _____atoms.

(1) 8 

(2) 9

(3) 7 

(4) 10

Ans. 1

Q 56. The order of electron affinity of O, S, N, and P is;

(1) O > P > S > N 

(2) O > N > S > P

(3) P > N > S > O 

(4) S > O > P > N

Ans. 4

Q 57. Which is the most abundant group 16 element?

(1) Oxygen 

(2) Sulphur

(3) Selenium 

(4) Tellurium

Ans. 1

Q 58. Which is the best oxidising agent among group 16 elements?

(1) Te 

(2) Se

(3) O 

(4) S

Ans. 3

Q 59. The minimum oxidation of sulphur possible is;

(1) –1 

(2) –2

(3) –4 

(4) –6

Ans. 2

Q 60. All the elements of the oxygen family are;

(1) Non-metals 

(2) Metalloids

(3) Radioactive 

(4) Polymorphic

Ans. 4

Q 61. Which of the following elements will have the highest atomic radii?

(1) Se 

(2) Te

(3) S 

(4) Po

Ans. 4

Q 62. There is a large difference between the melting and boiling point of oxygen and sulphur because;

(1) oxygen is more electronegative than sulphur.

(2) sulphur has less ionisation enthalpy than oxygen.

(3) oxygen exists as diatomic but sulphur as polyatomic.

(4) None of these

Ans. 3

Q 63. Which among the following group 16 elements exist in more than two allotropic states?

(1) Tellurium 

(2) Selenium

(3) Polonium 

(4) Oxygen

Ans. 2

Q 64. Group 16 Elements is also called;

(1) Pnicogens 

(2) Picogens

(3) Halogens 

(4) Chalcogens

Ans. 4

Q 65. The element that shows the highest number of allotropes among VIA group elements;

(1) S 

(2) Te

(3) Se 

(4) Po

Ans. 1

Q 66. Which of the following elements is metalloid?

(1) Selenium 

(2) Tellurium

(3) Both of these 

(4) None of these

Ans. 3

Q 67. Elements O, S, Se, and Te are commonly known as;

(1) Rare earth elements

(2) Chalcogens

(3) Halogens

(4) Pnictogens

Ans. 2

Q 68. Which of the following has the highest bond energy?

(1) O – O 

(2) S – S

(3) Se – Se 

(4) Te – Te

Ans. 2

Q 69. Air consists of _______ oxygen.

(1) 22% 

(2) 23%

(3) 21% 

(4) 24%

Ans. 3

Q 70. Statement-I: Catenation is maximum in sulphur up to 8 atoms.

Statement-II: At room temperature, sulphur exists as S4.

(1) Statement-I and Statement-II both are correct.

(2) Statement I is correct but Statement II is incorrect.

(3) Statement I is incorrect but Statement II is correct.

(4) Statement-I and Statement-II both are incorrect.

Ans. 2

Q 71. Oxygen is gas but sulphur is solid because;

(1) oxygen is composed of discrete molecules while sulphur is polymeric.

(2) molecular weight of sulphur is much higher than that of oxygen.

(3) oxygen is a stronger oxidising agent than sulphur.

(4) The boiling point of sulphur is much higher than that of oxygen.

Ans. 1

Q 72. Anomalous behaviour of oxygen is due to the following;

(1) high electronegativity.

(2) small atomic size.

(3) non-availability of d-orbital.

(4) All of these

Ans. 4

Q 73. Hydrides of oxygen and sulphur differ in the physical state due to;

(1) the presence of intermolecular hydrogen bonding in the hydrides of oxygen.

(2) more electronegativity of oxygen.

(3) stronger S–S bonds compared to O–O bonds.

(4) repulsion of lone pair of electrons on oxygen atoms.

Ans. 1

Q 74. The reducing property of hydrides of Group VIA elements generally;

(1) increases down the group.

(2) decreases down the group.

(3) remains constant down the group.

(4) fluctuates irregularly down the group.

Ans. 1

Q 75. The bond angle in hydrides of Group VIA elements generally;

(1) increases down the group.

(2) decreases down the group.

(3) remains constant down the group.

(4) fluctuates irregularly down the group.

Ans. 2

Q 76. Dioxygen gas is paramagnetic due to the presence of;

(1) lone pairs of electrons.

(2) unpaired electrons.

(3) double bonds.

(4) triple bonds.

Ans. 2

Q 77. At room temperature and pressure, dioxygen gas exists in which state of matter?

(1) Solid 

(2) Liquid

(3) Gas 

(4) Plasma

Ans. 3

Q 78. The color of pure dioxygen gas is;

(1) blue. 

(2) colourless.

(3) yellow. 

(4) green.

Ans. 2

Q 79. The oxide that is soluble in water and forms an acidic solution is;

(1) calcium oxide.

(2) aluminum oxide.

(3) carbon dioxide.

(4) sulfur dioxide.

Ans. 4

Q 80. An example of an amphoteric oxide is;

(1) calcium oxide.

(2) aluminum oxide.

(3) carbon dioxide.

(4) sulfur dioxide.

Ans. 2

Q 81. Amphoteric oxides exhibit properties of both;

(1) metals and non-metals.

(2) ionic and covalent compounds.

(3) basic and acidic oxides.

(4) reducing and oxidizing agents.

Ans. 3

Q 82. Ozone is;

(1) an isobar of oxygen.

(2) an isotope of oxygen.

(3) a polymer of oxygen.

(4) an allotrope of oxygen.

Ans. 4

How to Approach The p-Block Elements MCQs?

The following are some tips for approaching multiple-choice questions (MCQs) on p-block elements:

  1. Practice Regularly: Solve a range of MCQs to enhance your problem-solving abilities and pinpoint areas where you need improvement.
  2. Review Fundamental Concepts: Frequently revisit the basic principles of p-block elements to strengthen your understanding.
  3. Analyze Mistakes: When you make errors, carefully examine them to understand what went wrong and prevent similar mistakes in the future.
  4. Understand Key Concepts: Be knowledgeable about periodic trends, electronic configurations, and common valencies of p-block elements.
  5. Apply Concepts to Questions: Use periodic trends to predict properties, and be aware of common oxidation states and chemical reactions of p-block elements.

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The p-Block Elements MCQs FAQs

Q. What are p-block elements and why are they important for NEET?

Ans. p-Block elements are found in groups 13 to 18 of the periodic table and are crucial for NEET preparation. They are a major focus in the NEET Chemistry syllabus, covering key concepts like periodic trends and chemical properties.

Q. How can practicing p-block elements MCQs improve NEET preparation?

Ans. Regular practice with p-block elements MCQs helps reinforce your understanding of periodic trends, oxidation states, and chemical behaviors, enhancing problem-solving skills and exam performance.

Q. What should I focus on while studying p-block elements for NEET?

Ans. Focus on fundamental concepts such as periodic trends, electronic configurations, and the chemical properties of p-block elements. Consistent practice with MCQs will help solidify these concepts.

Q. How do MCQs with answers benefit NEET preparation?

Ans. MCQs with answers provide immediate feedback and detailed explanations, helping you identify and correct mistakes. This method enhances understanding and builds confidence for the NEET exam.

Q. How can Class 12 students use p-block elements MCQs effectively?

Ans. Class 12 students should study the fundamental concepts of p-block elements in detail and practice MCQs regularly. Using class notes, textbooks, and additional resources will help improve accuracy and speed.

Q. What strategies should I use to approach p-block elements MCQs?

Ans. Regularly practice a variety of MCQs, review key concepts frequently, and analyze mistakes to understand errors. Familiarize yourself with periodic trends and common oxidation states to apply concepts effectively during the exam.

To succeed in the NEET/JEE exams and score good marks in class 12 chemistry, it is essential to thoroughly understand p-block elements through multiple-choice questions (MCQs). p-Block elements, which are located in groups 13 to 18 of the periodic table, are a major focus in the NEET/JEE/CBSE Board Class 12 Chemistry syllabus. The p-Block Elements MCQs evaluate your knowledge of key concepts such as periodic trends, electronic configurations, and the chemical properties of these elements. 

By regularly practicing p-block elements MCQs, you can improve your problem-solving skills and become familiar with the types of questions that may appear on the exam. This consistent practice will help you be better prepared and increase your chances of doing well in the NEET/JEE/CBSE Board exams. Students can practice the p-Block Elements MCQs provided in the article below.

The p-Block Elements MCQs NEET/JEE

For NEET/JEE/CBSE Board preparation, practicing MCQs on p-block elements is essential. These questions evaluate your understanding of key concepts such as periodic trends, oxidation states, and the chemical properties of these elements. Regularly working on these MCQs helps you remember and apply your knowledge more effectively during the exam, thereby improving your performance. 

Furthermore, reviewing previous year questions related to p-block elements can give you valuable insights into common question formats and exam patterns, allowing you to adjust your study strategy accordingly.

The p-Block Elements MCQs Class 12

In Class 12, p-block elements are a crucial component of the Chemistry syllabus, affecting both board exams and NEET/JEE preparation. To handle questions about this topic effectively, a thorough understanding of p-block elements is essential. Start by studying the fundamental concepts related to these elements in detail. 

Regular practice with MCQs helps reinforce these concepts, improving both your accuracy and speed in answering questions. To strengthen your grasp of the subject, make use of class notes, textbooks, and additional practice materials. This comprehensive approach will ensure you are well-prepared for both your board exams and the NEET/JEE exams.

Er. Neeraj K.Anand is a freelance mentor and writer who specializes in Engineering & Science subjects. Neeraj Anand received a B.Tech degree in Electronics and Communication Engineering from N.I.T Warangal & M.Tech Post Graduation from IETE, New Delhi. He has over 30 years of teaching experience and serves as the Head of Department of ANAND CLASSES. He concentrated all his energy and experiences in academics and subsequently grew up as one of the best mentors in the country for students aspiring for success in competitive examinations. In parallel, he started a Technical Publication "ANAND TECHNICAL PUBLISHERS" in 2002 and Educational Newspaper "NATIONAL EDUCATION NEWS" in 2014 at Jalandhar. Now he is a Director of leading publication "ANAND TECHNICAL PUBLISHERS", "ANAND CLASSES" and "NATIONAL EDUCATION NEWS". He has published more than hundred books in the field of Physics, Mathematics, Computers and Information Technology. Besides this he has written many books to help students prepare for IIT-JEE and AIPMT entrance exams. He is an executive member of the IEEE (Institute of Electrical & Electronics Engineers. USA) and honorary member of many Indian scientific societies such as Institution of Electronics & Telecommunication Engineers, Aeronautical Society of India, Bioinformatics Institute of India, Institution of Engineers. He has got award from American Biographical Institute Board of International Research in the year 2005.