Thermodynamics-Laws Of Thermodynamics, Applications with Examples

February 11, 2025December 13, 2024 by Neeraj Anand, Param Anand

What is Thermodynamics?

The branch which deals with the movement of energy from one form to the other and the relation between heat and temperature with energy and work done is called as thermodynamics.

In other terms we can define thermodynamics as the science stream that deals with the study of the combined effects of heat and work on the changes of state of matter confined by the laws of thermodynamics.

Chemical reactions which releases heat energy associated with it are converted into different usable forms based on the laws of thermodynamics. The fact that energy can only be transformed from one form to the other forms and its use in different industries is on the basis of energy transformation.

We are aware that chemical reactions have energy associated with it. The laws of thermodynamics deal with energy changes during a reaction and are not concerned with the rate at which the reaction is proceeding.

Define Chemical Thermodynamics

Chemical thermodynamics is the study of relation between work, heat and chemical reactions or with the physical changes of the state which are confined to the laws of thermodynamics.

Some general terms like heat, energy, and work were done are often used in thermodynamics. Let us learn a bit about basic thermodynamics and understand these terms.

Internal Energy

It referred to the energy content within the system. The energy represents the overall energy of the system and may include many forms of energy such as potential energy, kinetic energy etc. In a chemical reaction, we know about the energy transformations and basic thermodynamics provides us with the information regarding energy change associated with the particles of the system.

Factors Affecting the Internal Energy

The internal energy of a system may change when:

Heat passes into or out of the system,
Work is done on or by the system or matter enters or leaves the system.

Work

Work done by a system is defined as the quantity of energy exchanged between a system and its surroundings. Work is completely governed by external factors such as an external force, pressure or volume or change in temperature etc.

Heat

Heat in thermodynamics is defined as the kinetic energy of the molecules of the substance. Heat and the thermodynamics together form the basics which helped process designers and engineers to optimize their processes and harness the energy associated with chemical reactions economically. Heat energy flows from higher temperature to lower temperature.

Thermodynamic System and the Surrounding

Thermodynamics defines a system as the part of the universe under study that is the part where observations are made. The surrounding and universe interact with each other and depending on the type of the system, exchange of matter and energies occur.

The system’s classification entirely depends on the movement of energy and matter in or out of the system. There are two types of system:

Open System:

Those systems where the exchange of energy, as well as matter takes place, are treated as an open system. For example, water is boiled on a stove without it being covered, the container behaves as an open system because it receives heat energy from an external source and the matter being released are water vapours.

Closed System:

A closed system is referred to the system where only energy can be exchanged with the surrounding and not the matter. It can also be said that a closed system has a constant amount of matter and only the energy of the system can be changed. For instance, when we keep a shield bottle of water in the fridge, the loss of energy to the surrounding will result in the temperature of the water inside it going down even though the quantity of water in the bottle remains the same.

Isolated System:

In case of isolated systems, neither energy nor matter can be exchanged between the system and the surrounding. An example of an isolated system is a Thermos flask.

Let us see the major aspects on which environment can affect the thermodynamics of a system.

There are four laws which govern the thermodynamic systems’ phenomena, they are:

Laws of Thermodynamics

First law of thermodynamics: When energy moves into or out of a system, the system’s internal energy changes in accordance with the law of conservation of mass.
Second law of thermodynamics: The state of the entropy of the entire universe, as an isolated system, will always increase over time.
Third law of thermodynamics: Entropy of a perfect crystal at absolute zero is zero.

The laws of thermodynamics were the most important lesson for people understanding the mechanism behind phase change of matter.

Frequently Asked Questions – FAQs

What are the basic concepts of thermodynamics?

Thermodynamics, the study of heat, labour, temperature and energy relationships. Thermodynamics is in general terms, concerned with the transition of energy from one position to another and from one form to another. The basic point is that heat is an energy form that corresponds to a specific amount of mechanical activity.

What is the purpose of thermodynamics?

The branch of physics concerned with the interactions between heat and other sources of energy is thermodynamics. It explains, in particular, how thermal energy is transferred into and from other sources of energy and how it affects matter.

Who gave laws of thermodynamics?

Rudolf Clausius and William Thomson (Kelvin) stated both the First Law – which preserves total energy – and the Second Law of Thermodynamics around 1850. Initially, the Second Law was conceived in terms of the fact that heat does not flow from a cooler body to a hotter one naturally.

How is thermodynamics used in everyday life?

The human body obeys thermodynamic rules. It evaporates from the body as the sweat consumes more and more heat, getting more disordered and adding heat to the air, which heats up the room’s air temperature. Many sweaty people in the “closed system” of a crowded space will heat it up fast.

What is the 2nd law of thermodynamics in simple terms?

The Second Law of Thermodynamics notes that processes requiring heat energy transport or conversion are irreversible. … The Second Law also notes that every isolated structure has a normal propensity to degenerate into a more disordered state.

Neeraj Anand, Param Anand

Er. Neeraj K.Anand is a freelance mentor and writer who specializes in Engineering & Science subjects. Neeraj Anand received a B.Tech degree in Electronics and Communication Engineering from N.I.T Warangal & M.Tech Post Graduation from IETE, New Delhi. He has over 30 years of teaching experience and serves as the Head of Department of ANAND CLASSES. He concentrated all his energy and experiences in academics and subsequently grew up as one of the best mentors in the country for students aspiring for success in competitive examinations. In parallel, he started a Technical Publication "ANAND TECHNICAL PUBLISHERS" in 2002 and Educational Newspaper "NATIONAL EDUCATION NEWS" in 2014 at Jalandhar. Now he is a Director of leading publication "ANAND TECHNICAL PUBLISHERS", "ANAND CLASSES" and "NATIONAL EDUCATION NEWS". He has published more than hundred books in the field of Physics, Mathematics, Computers and Information Technology. Besides this he has written many books to help students prepare for IIT-JEE and AIPMT entrance exams. He is an executive member of the IEEE (Institute of Electrical & Electronics Engineers. USA) and honorary member of many Indian scientific societies such as Institution of Electronics & Telecommunication Engineers, Aeronautical Society of India, Bioinformatics Institute of India, Institution of Engineers. He has got award from American Biographical Institute Board of International Research in the year 2005.

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CBSE Class 11 Chemistry Syllabus

CBSE Class 11 Chemistry Syllabus is a vast which needs a clear understanding of the concepts and topics. Knowing CBSE Class 11 Chemistry syllabus helps students to understand the course structure of Chemistry.

Unit-wise CBSE Class 11 Syllabus for Chemistry

Below is a list of detailed information on each unit for Class 11 Students.

UNIT I – Some Basic Concepts of Chemistry

General Introduction: Importance and scope of Chemistry.

Nature of matter, laws of chemical combination, Dalton’s atomic theory: concept of elements,
atoms and molecules.

Atomic and molecular masses, mole concept and molar mass, percentage composition, empirical and molecular formula, chemical reactions, stoichiometry and calculations based on stoichiometry.

UNIT II – Structure of Atom

Discovery of Electron, Proton and Neutron, atomic number, isotopes and isobars. Thomson’s model and its limitations. Rutherford’s model and its limitations, Bohr’s model and its limitations, concept of shells and subshells, dual nature of matter and light, de Broglie’s relationship, Heisenberg uncertainty principle, concept of orbitals, quantum numbers, shapes of s, p and d orbitals, rules for filling electrons in orbitals – Aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of atoms, stability of half-filled and completely filled orbitals.

UNIT III – Classification of Elements and Periodicity in Properties

Significance of classification, brief history of the development of periodic table, modern periodic law and the present form of periodic table, periodic trends in properties of elements -atomic radii, ionic radii, inert gas radii, Ionization enthalpy, electron gain enthalpy, electronegativity, valency. Nomenclature of elements with atomic number greater than 100.

UNIT IV – Chemical Bonding and Molecular Structure

Valence electrons, ionic bond, covalent bond, bond parameters, Lewis structure, polar character of covalent bond, covalent character of ionic bond, valence bond theory, resonance, geometry of covalent molecules, VSEPR theory, concept of hybridization, involving s, p and d orbitals and shapes of some simple molecules, molecular orbital theory of homonuclear diatomic molecules(qualitative idea only), Hydrogen bond.

UNIT V – Chemical Thermodynamics

Concepts of System and types of systems, surroundings, work, heat, energy, extensive and intensive properties, state functions. First law of thermodynamics – internal energy and enthalpy, measurement of U and H, Hess’s law of constant heat summation, enthalpy of bond dissociation, combustion, formation, atomization, sublimation, phase transition, ionization, solution and dilution. Second law of Thermodynamics (brief introduction)
Introduction of entropy as a state function, Gibb’s energy change for spontaneous and nonspontaneous processes.
Third law of thermodynamics (brief introduction).

UNIT VI – Equilibrium

Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of mass action, equilibrium constant, factors affecting equilibrium – Le Chatelier’s principle, ionic equilibrium- ionization of acids and bases, strong and weak electrolytes, degree of ionization,
ionization of poly basic acids, acid strength, concept of pH, hydrolysis of salts (elementary idea), buffer solution, Henderson Equation, solubility product, common ion effect (with illustrative examples).

UNIT VII – Redox Reactions

Concept of oxidation and reduction, redox reactions, oxidation number, balancing redox reactions, in terms of loss and gain of electrons and change in oxidation number, applications of redox reactions.

UNIT VIII – Organic Chemistry: Some basic Principles and Techniques

General introduction, classification and IUPAC nomenclature of organic compounds. Electronic displacements in a covalent bond: inductive effect, electromeric effect, resonance and hyper conjugation. Homolytic and heterolytic fission of a covalent bond: free radicals, carbocations, carbanions, electrophiles and nucleophiles, types of organic reactions.

UNIT IX – Hydrocarbons

Classification of Hydrocarbons
Aliphatic Hydrocarbons:
Alkanes – Nomenclature, isomerism, conformation (ethane only), physical properties, chemical reactions.
Alkenes – Nomenclature, structure of double bond (ethene), geometrical isomerism, physical properties, methods of preparation, chemical reactions: addition of hydrogen, halogen, water, hydrogen halides (Markovnikov’s addition and peroxide effect), ozonolysis, oxidation, mechanism of electrophilic addition.
Alkynes – Nomenclature, structure of triple bond (ethyne), physical properties, methods of preparation, chemical reactions: acidic character of alkynes, addition reaction of – hydrogen, halogens, hydrogen halides and water.

Aromatic Hydrocarbons:

Introduction, IUPAC nomenclature, benzene: resonance, aromaticity, chemical properties: mechanism of electrophilic substitution. Nitration, sulphonation, halogenation, Friedel Craft’s alkylation and acylation, directive influence of functional group in monosubstituted benzene. Carcinogenicity and toxicity.

To know the CBSE Syllabus for all the classes from 1 to 12, visit the Syllabus page of CBSE. Meanwhile, to get the Practical Syllabus of Class 11 Chemistry, read on to find out more about the syllabus and related information in this page.

CBSE Class 11 Chemistry Practical Syllabus with Marking Scheme

In Chemistry subject, practical also plays a vital role in improving their academic scores in the subject. The overall weightage of Chemistry practical mentioned in the CBSE Class 11 Chemistry syllabus is 30 marks. So, students must try their best to score well in practicals along with theory. It will help in increasing their overall academic score.

CBSE Class 11 Chemistry Practical Syllabus

The experiments will be conducted under the supervision of subject teacher. CBSE Chemistry Practicals is for 30 marks. This contribute to the overall practical marks for the subject.

The table below consists of evaluation scheme of practical exams.

Evaluation Scheme	Marks
Volumetric Analysis	08
Salt Analysis	08
Content Based Experiment	06
Project Work	04
Class record and viva	04
Total	30

CBSE Syllabus for Class 11 Chemistry Practical

Micro-chemical methods are available for several of the practical experiments. Wherever possible such techniques should be used.

A. Basic Laboratory Techniques
1. Cutting glass tube and glass rod
2. Bending a glass tube
3. Drawing out a glass jet
4. Boring a cork

B. Characterization and Purification of Chemical Substances
1. Determination of melting point of an organic compound.
2. Determination of boiling point of an organic compound.
3. Crystallization of impure sample of any one of the following: Alum, Copper Sulphate, Benzoic Acid.

C. Experiments based on pH

1. Any one of the following experiments:

Determination of pH of some solutions obtained from fruit juices, solution of known and varied concentrations of acids, bases and salts using pH paper or universal indicator.
Comparing the pH of solutions of strong and weak acids of same concentration.
Study the pH change in the titration of a strong base using universal indicator.

2. Study the pH change by common-ion in case of weak acids and weak bases.

D. Chemical Equilibrium
One of the following experiments:

1. Study the shift in equilibrium between ferric ions and thiocyanate ions by increasing/decreasing the concentration of either of the ions.
2. Study the shift in equilibrium between [Co(H₂O)₆] ²⁺ and chloride ions by changing the concentration of either of the ions.

E. Quantitative Estimation
i. Using a mechanical balance/electronic balance.
ii. Preparation of standard solution of Oxalic acid.
iii. Determination of strength of a given solution of Sodium hydroxide by titrating it against standard solution of Oxalic acid.
iv. Preparation of standard solution of Sodium carbonate.
v. Determination of strength of a given solution of hydrochloric acid by titrating it against standard Sodium Carbonatesolution.

F. Qualitative Analysis
1) Determination of one anion and one cation in a given salt
Cations‐ Pb²⁺, Cu²⁺, As³⁺, Al³⁺, Fe³⁺, Mn²⁺, Ni²⁺, Zn²⁺, Co²⁺, Ca²⁺, Sr²⁺, Ba²⁺, Mg²⁺, NH₄ ⁺
Anions – (CO₃)^2‐ , S^2‐, NO₂^‐ , SO₃^2‐, SO^2‐ , NO ^‐ , Cl^‐ , Br^‐, I‐, PO₄^3‐ , C₂O²‐ ,CH₃COO^‐
(Note: Insoluble salts excluded)

2) Detection of ‐ Nitrogen, Sulphur, Chlorine in organic compounds.

G) PROJECTS
Scientific investigations involving laboratory testing and collecting information from other sources.

A few suggested projects are as follows:

Checking the bacterial contamination in drinking water by testing sulphide ion
Study of the methods of purification of water.
Testing the hardness, presence of Iron, Fluoride, Chloride, etc., depending upon the regional
variation in drinking water and study of causes of presence of these ions above permissible
limit (if any).
Investigation of the foaming capacity of different washing soaps and the effect of addition of
Sodium carbonate on it.
Study the acidity of different samples of tea leaves.
Determination of the rate of evaporation of different liquids Study the effect of acids and
bases on the tensile strength of fibres.
Study of acidity of fruit and vegetable juices.

Note: Any other investigatory project, which involves about 10 periods of work, can be chosen with the approval of the teacher.

Practical Examination for Visually Impaired Students of Class 11

Below is a list of practicals for the visually impaired students.

A. List of apparatus for identification for assessment in practicals (All experiments)
Beaker, tripod stand, wire gauze, glass rod, funnel, filter paper, Bunsen burner, test tube, test tube stand,
dropper, test tube holder, ignition tube, china dish, tongs, standard flask, pipette, burette, conical flask, clamp
stand, dropper, wash bottle
• Odour detection in qualitative analysis
• Procedure/Setup of the apparatus

B. List of Experiments A. Characterization and Purification of Chemical Substances
1. Crystallization of an impure sample of any one of the following: copper sulphate, benzoic acid
B. Experiments based on pH
1. Determination of pH of some solutions obtained from fruit juices, solutions of known and varied
concentrations of acids, bases and salts using pH paper
2. Comparing the pH of solutions of strong and weak acids of same concentration.

C. Chemical Equilibrium
1. Study the shift in equilibrium between ferric ions and thiocyanate ions by increasing/decreasing
the concentration of eitherions.
2. Study the shift in equilibrium between [Co(H2O)6]2+ and chloride ions by changing the
concentration of either of the ions.

D. Quantitative estimation
1. Preparation of standard solution of oxalic acid.
2. Determination of molarity of a given solution of sodium hydroxide by titrating it against standard
solution of oxalic acid.

E. Qualitative Analysis
1. Determination of one anion and one cation in a given salt
2. Cations – NH+4
Anions – (CO3)2-, S2-, (SO3)2-, Cl-, CH3COO-
(Note: insoluble salts excluded)
3. Detection of Nitrogen in the given organic compound.
4. Detection of Halogen in the given organic compound.

Note: The above practicals may be carried out in an experiential manner rather than recording observations.

We hope students must have found this information on CBSE Syllabus useful for their studying Chemistry. Learn Maths & Science in interactive and fun loving ways with ANAND CLASSES (A School Of Competitions) App/Tablet.

Frequently Asked Questions on CBSE Class 11 Chemistry Syllabus

How many units are in the CBSE Class 11 Chemistry Syllabus?

There are 9 units in the CBSE Class 11 Chemistry Syllabus. Students can access various study materials for the chapters mentioned in this article for free at ANAND CLASSES (A School Of Competitions).

What is the total marks for practicals examination as per the CBSE Class 11 Chemistry Syllabus?

The total marks for the practicals as per the CBSE Class 11 Chemistry Syllabus is 30. It includes volumetric analysis, content-based experiment, salt analysis, class record, project work and viva.

Which chapter carries more weightage as per the CBSE Syllabus for Class 11 Chemistry?

The organic chemistry chapter carries more weightage as per the CBSE Syllabus for Class 11 Chemistry.