Solved Examples | Prediction of Period, Group, and Block of Element in Periodic Table Using Electronic Configuration

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🧪 Solved Examples – Prediction of Element Position in the Periodic Table

Q: Predict the position of an element in the periodic table having the electronic configuration of (n–1)d1ns2 for n = 4. [NCERT]

Solution: Given: n = 4
Electronic configuration = 3d1 4s2

✅ The last electron enters the 3d orbital, so it’s a d-block element.

👉 Group number = electrons in (n−1)d + electrons in ns
Group number = 1 (from 3d) + 2 (from 4s) = 3

🧾 Final Answer:

  • Block: d-block
  • Group: 3
  • Period: 4

Q: (a) Elements A, B, C, and D have atomic numbers 12, 19, 29, and 36 respectively. Identify their groups based on electronic configuration. (b) Predict their blocks, periods, and groups. (c) Which of these are representative elements? [NCERT]

Solution:(a) Electronic Configuration and Group No. :

ElementAtomic NumberElectronic ConfigurationGroup
A121s² 2s² 2p⁶ 3s²2
B191s² 2s² 2p⁶ 3s² 3p⁶ 4s¹1
C291s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹11
D361s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶18

(b) Prediction of Block, Period, and Group:

  • A (Z = 12):
    • Last electron → 3s orbital ⇒ s-block
    • Period = 3rd
    • Group = Valence electrons = 2
  • B (Z = 19):
    • Last electron → 4s orbital ⇒ s-block
    • Period = 4th
    • Group = Valence electrons = 1
  • C (Z = 29):
    • Last electron → 3d orbital ⇒ d-block
    • Period = 4th
    • Group = (3d¹⁰ + 4s¹) = 11
  • D (Z = 36):
    • Last electron → 4p orbital ⇒ p-block
    • Period = 4th
    • Group = 10 + valence electrons = 10 + 8 = 18

(c) Representative Elements:

✔️ A (Z = 12) and B (Z = 19) are representative elements (s- and p-block main group elements).


Q: Identify the elements based on their electronic configurations. Also, answer the questions given below: [NCERT]
ConfigurationElement
(i) 1s² 2s² 2p⁶ 3s¹Sodium (Na)
(ii) 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹Scandium (Sc)
(iii) 1s² 2s² 2p³Nitrogen (N)
(iv) 1s² 2s² 2p⁶ 3s²Calcium (Ca)
(v) 1s² 2s² 2p⁶ 3s² 3p⁵Chlorine (Cl)
(vi) 1s² 2s² 2p⁶ 3s² 3p³Phosphorus (P)
(vii) 1s² 2s² 2p⁶Neon (Ne)
(viii) 1s² 2s² 2p⁶ 3s² 3p⁴Sulphur (S)

Answers:

  1. Alkaline earth metal: Calcium (iv)
  2. Lowest chemical reactivity: Neon (vii)
  3. Group 15 elements: Nitrogen (iii), Phosphorus (vi)
  4. Transition element: Scandium (ii)
  5. Halogen: Chlorine (v)
  6. p-block elements: Nitrogen, Chlorine, Phosphorus, Neon, Sulphur
  7. Second period elements: Nitrogen (iii), Neon (vii)

Q: The electronic configurations of the elements are as follows:
ElementElectronic Configuration
A1s² 2s² 2p¹
B1s² 2s² 2p⁶ 3s² 3p¹
C1s² 2s² 2p⁶ 3s² 3p³
D1s² 2s² 2p⁶ 3s² 3p⁵
E1s² 2s² 2p⁶ 3s² 3p⁶ 4s²
Which of these elements belong to the same group in the periodic table? [NCERT]

Solution: Elements with the same number of valence electrons belong to the same group.

✔️ Element A and B both have 3 valence electrons → belong to Group 13.


Q. The elements Z = 107, 108 and Z = 109 have been made recently. Indicate the group in which you will place the above elements. [NCERT]

Solution: In recent times, scientists have successfully created new superheavy elements with atomic numbers 107, 108, and 109. Let’s understand how to predict their position in the periodic table using their electronic configurations.

🧪 Electronic Configurations:

  • Z = 107 → [Rn] 5f¹⁴ 6d⁵ 7s²
  • Z = 108 → [Rn] 5f¹⁴ 6d⁶ 7s²
  • Z = 109 → [Rn] 5f¹⁴ 6d⁷ 7s²

✅ In all three cases, the last electrons enter the 6d subshell, which means these elements belong to the d-block (transition elements).

📌 Group Prediction:

To find the group number for d-block elements, we use the rule:

Group number = Number of electrons in (n–1)d subshell + Number of electrons in the valence (ns) shell

Let’s apply the formula:

Atomic NumberConfigurationd-electronss-electronsGroup Number
Z = 1076d⁵ 7s²527
Z = 1086d⁶ 7s²628
Z = 1096d⁷ 7s²729

Final Answer:

  • Element 107Group 7
  • Element 108Group 8
  • Element 109Group 9
  • All are part of the d-block in the periodic table.

🔖 These elements are classified as superheavy transition metals, and their chemical properties are still under active research. However, based on periodic trends and electronic configurations, their group placement follows standard rules.


📝 Conclusion:

By analyzing electronic configurations, we can accurately predict an element’s:

  • Block (s, p, d, f)
  • Period (from the valence shell)
  • Group (using rules for each block)

This knowledge is essential for understanding trends in the periodic table and solving problems in competitive exams.


🔖 Related Topics:


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⬅️ Prediction of Period, Group, and Block of a Given Element in Periodic Table Short Periods Elements ➡️

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