Anand Classes explain how To find the position of an element in the periodic table, we can use its electronic configuration. This helps us easily determine the period, group, and block to which the element belongs. In this post, weโll go through simple solved examples to understand how to apply these rules step by step. This is very helpful for students preparing for JEE, NEET, and CBSE Class 11 exams.
Table of Contents
๐งช Solved Examples – Prediction of Element Position in the Periodic Table
Q: Predict the position of an element in the periodic table having the electronic configuration of (nโ1)d1ns2 for n = 4. [NCERT]
Solution: Given: n = 4
Electronic configuration = 3d1 4s2
โ The last electron enters the 3d orbital, so it’s a d-block element.
๐ Group number = electrons in (nโ1)d + electrons in ns
Group number = 1 (from 3d) + 2 (from 4s) = 3
๐งพ Final Answer:
- Block: d-block
- Group: 3
- Period: 4
Q: (a) Elements A, B, C, and D have atomic numbers 12, 19, 29, and 36 respectively. Identify their groups based on electronic configuration. (b) Predict their blocks, periods, and groups. (c) Which of these are representative elements? [NCERT]
Solution: โ (a) Electronic Configuration and Group No. :
| Element | Atomic Number | Electronic Configuration | Group |
|---|---|---|---|
| A | 12 | 1sยฒ 2sยฒ 2pโถ 3sยฒ | 2 |
| B | 19 | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยน | 1 |
| C | 29 | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 3dยนโฐ 4sยน | 11 |
| D | 36 | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 3dยนโฐ 4sยฒ 4pโถ | 18 |
โ (b) Prediction of Block, Period, and Group:
- A (Z = 12):
- Last electron โ 3s orbital โ s-block
- Period = 3rd
- Group = Valence electrons = 2
- B (Z = 19):
- Last electron โ 4s orbital โ s-block
- Period = 4th
- Group = Valence electrons = 1
- C (Z = 29):
- Last electron โ 3d orbital โ d-block
- Period = 4th
- Group = (3dยนโฐ + 4sยน) = 11
- D (Z = 36):
- Last electron โ 4p orbital โ p-block
- Period = 4th
- Group = 10 + valence electrons = 10 + 8 = 18
โ (c) Representative Elements:
โ๏ธ A (Z = 12) and B (Z = 19) are representative elements (s- and p-block main group elements).
Q: Identify the elements based on their electronic configurations. Also, answer the questions given below: [NCERT]
| Configuration | Element |
|---|---|
| (i) 1sยฒ 2sยฒ 2pโถ 3sยน | Sodium (Na) |
| (ii) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยฒ 3dยน | Scandium (Sc) |
| (iii) 1sยฒ 2sยฒ 2pยณ | Nitrogen (N) |
| (iv) 1sยฒ 2sยฒ 2pโถ 3sยฒ | Calcium (Ca) |
| (v) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโต | Chlorine (Cl) |
| (vi) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยณ | Phosphorus (P) |
| (vii) 1sยฒ 2sยฒ 2pโถ | Neon (Ne) |
| (viii) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโด | Sulphur (S) |
โ Answers:
- Alkaline earth metal: Calcium (iv)
- Lowest chemical reactivity: Neon (vii)
- Group 15 elements: Nitrogen (iii), Phosphorus (vi)
- Transition element: Scandium (ii)
- Halogen: Chlorine (v)
- p-block elements: Nitrogen, Chlorine, Phosphorus, Neon, Sulphur
- Second period elements: Nitrogen (iii), Neon (vii)
Q: The electronic configurations of the elements are as follows:
| Element | Electronic Configuration |
|---|---|
| A | 1sยฒ 2sยฒ 2pยน |
| B | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยน |
| C | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยณ |
| D | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโต |
| E | 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยฒ |
Which of these elements belong to the same group in the periodic table? [NCERT]
Solution: Elements with the same number of valence electrons belong to the same group.
โ๏ธ Element A and B both have 3 valence electrons โ belong to Group 13.
Q. The elements Z = 107, 108 and Z = 109 have been made recently. Indicate the group in which you will place the above elements. [NCERT]
Solution: In recent times, scientists have successfully created new superheavy elements with atomic numbers 107, 108, and 109. Letโs understand how to predict their position in the periodic table using their electronic configurations.
๐งช Electronic Configurations:
- Z = 107 โ [Rn] 5fยนโด 6dโต 7sยฒ
- Z = 108 โ [Rn] 5fยนโด 6dโถ 7sยฒ
- Z = 109 โ [Rn] 5fยนโด 6dโท 7sยฒ
โ In all three cases, the last electrons enter the 6d subshell, which means these elements belong to the d-block (transition elements).
๐ Group Prediction:
To find the group number for d-block elements, we use the rule:
Group number = Number of electrons in (nโ1)d subshell + Number of electrons in the valence (ns) shell
Let’s apply the formula:
| Atomic Number | Configuration | d-electrons | s-electrons | Group Number |
|---|---|---|---|---|
| Z = 107 | 6dโต 7sยฒ | 5 | 2 | 7 |
| Z = 108 | 6dโถ 7sยฒ | 6 | 2 | 8 |
| Z = 109 | 6dโท 7sยฒ | 7 | 2 | 9 |
โ Final Answer:
- Element 107 โ Group 7
- Element 108 โ Group 8
- Element 109 โ Group 9
- All are part of the d-block in the periodic table.
๐ These elements are classified as superheavy transition metals, and their chemical properties are still under active research. However, based on periodic trends and electronic configurations, their group placement follows standard rules.
๐ Conclusion:
By analyzing electronic configurations, we can accurately predict an element’s:
- Block (s, p, d, f)
- Period (from the valence shell)
- Group (using rules for each block)
This knowledge is essential for understanding trends in the periodic table and solving problems in competitive exams.
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