Solved Examples | Prediction of Period, Group, and Block of Element in Periodic Table Using Electronic Configuration

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๐Ÿงช Solved Examples – Prediction of Element Position in the Periodic Table

Q: Predict the position of an element in the periodic table having the electronic configuration of (nโ€“1)d1ns2 for n = 4. [NCERT]

Solution: Given: n = 4
Electronic configuration = 3d1 4s2

โœ… The last electron enters the 3d orbital, so it’s a d-block element.

๐Ÿ‘‰ Group number = electrons in (nโˆ’1)d + electrons in ns
Group number = 1 (from 3d) + 2 (from 4s) = 3

๐Ÿงพ Final Answer:

  • Block: d-block
  • Group: 3
  • Period: 4

Q: (a) Elements A, B, C, and D have atomic numbers 12, 19, 29, and 36 respectively. Identify their groups based on electronic configuration. (b) Predict their blocks, periods, and groups. (c) Which of these are representative elements? [NCERT]

Solution: โœ… (a) Electronic Configuration and Group No. :

ElementAtomic NumberElectronic ConfigurationGroup
A121sยฒ 2sยฒ 2pโถ 3sยฒ2
B191sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยน1
C291sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 3dยนโฐ 4sยน11
D361sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 3dยนโฐ 4sยฒ 4pโถ18

โœ… (b) Prediction of Block, Period, and Group:

  • A (Z = 12):
    • Last electron โ†’ 3s orbital โ‡’ s-block
    • Period = 3rd
    • Group = Valence electrons = 2
  • B (Z = 19):
    • Last electron โ†’ 4s orbital โ‡’ s-block
    • Period = 4th
    • Group = Valence electrons = 1
  • C (Z = 29):
    • Last electron โ†’ 3d orbital โ‡’ d-block
    • Period = 4th
    • Group = (3dยนโฐ + 4sยน) = 11
  • D (Z = 36):
    • Last electron โ†’ 4p orbital โ‡’ p-block
    • Period = 4th
    • Group = 10 + valence electrons = 10 + 8 = 18

โœ… (c) Representative Elements:

โœ”๏ธ A (Z = 12) and B (Z = 19) are representative elements (s- and p-block main group elements).


Q: Identify the elements based on their electronic configurations. Also, answer the questions given below: [NCERT]
ConfigurationElement
(i) 1sยฒ 2sยฒ 2pโถ 3sยนSodium (Na)
(ii) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยฒ 3dยนScandium (Sc)
(iii) 1sยฒ 2sยฒ 2pยณNitrogen (N)
(iv) 1sยฒ 2sยฒ 2pโถ 3sยฒCalcium (Ca)
(v) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโตChlorine (Cl)
(vi) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยณPhosphorus (P)
(vii) 1sยฒ 2sยฒ 2pโถNeon (Ne)
(viii) 1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโดSulphur (S)

โœ… Answers:

  1. Alkaline earth metal: Calcium (iv)
  2. Lowest chemical reactivity: Neon (vii)
  3. Group 15 elements: Nitrogen (iii), Phosphorus (vi)
  4. Transition element: Scandium (ii)
  5. Halogen: Chlorine (v)
  6. p-block elements: Nitrogen, Chlorine, Phosphorus, Neon, Sulphur
  7. Second period elements: Nitrogen (iii), Neon (vii)

Q: The electronic configurations of the elements are as follows:
ElementElectronic Configuration
A1sยฒ 2sยฒ 2pยน
B1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยน
C1sยฒ 2sยฒ 2pโถ 3sยฒ 3pยณ
D1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโต
E1sยฒ 2sยฒ 2pโถ 3sยฒ 3pโถ 4sยฒ
Which of these elements belong to the same group in the periodic table? [NCERT]

Solution: Elements with the same number of valence electrons belong to the same group.

โœ”๏ธ Element A and B both have 3 valence electrons โ†’ belong to Group 13.


Q. The elements Z = 107, 108 and Z = 109 have been made recently. Indicate the group in which you will place the above elements. [NCERT]

Solution: In recent times, scientists have successfully created new superheavy elements with atomic numbers 107, 108, and 109. Letโ€™s understand how to predict their position in the periodic table using their electronic configurations.

๐Ÿงช Electronic Configurations:

  • Z = 107 โ†’ [Rn] 5fยนโด 6dโต 7sยฒ
  • Z = 108 โ†’ [Rn] 5fยนโด 6dโถ 7sยฒ
  • Z = 109 โ†’ [Rn] 5fยนโด 6dโท 7sยฒ

โœ… In all three cases, the last electrons enter the 6d subshell, which means these elements belong to the d-block (transition elements).

๐Ÿ“Œ Group Prediction:

To find the group number for d-block elements, we use the rule:

Group number = Number of electrons in (nโ€“1)d subshell + Number of electrons in the valence (ns) shell

Let’s apply the formula:

Atomic NumberConfigurationd-electronss-electronsGroup Number
Z = 1076dโต 7sยฒ527
Z = 1086dโถ 7sยฒ628
Z = 1096dโท 7sยฒ729

โœ… Final Answer:

  • Element 107 โ†’ Group 7
  • Element 108 โ†’ Group 8
  • Element 109 โ†’ Group 9
  • All are part of the d-block in the periodic table.

๐Ÿ”– These elements are classified as superheavy transition metals, and their chemical properties are still under active research. However, based on periodic trends and electronic configurations, their group placement follows standard rules.


๐Ÿ“ Conclusion:

By analyzing electronic configurations, we can accurately predict an element’s:

  • Block (s, p, d, f)
  • Period (from the valence shell)
  • Group (using rules for each block)

This knowledge is essential for understanding trends in the periodic table and solving problems in competitive exams.


๐Ÿ”– Related Topics:


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โฌ…๏ธ Prediction of Period, Group, and Block of a Given Element in Periodic Table Short Periods Elements โžก๏ธ

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