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s-Block Elements | Group 1 and Group 2 Elements | Class 11 CBSE Notes

🧪 Classification of Elements into s-Block Elements

🌟 s-Block Elements: An Overview

The elements of the periodic table in which the last electron enters the s-orbital are known as s-block elements. The s-orbital can accommodate a maximum of two electrons.

👉 General Electronic Configuration: ns1−2, where n = 1 to 7.


🔷 Group 1 Elements – Alkali Metals

🧪 What Are Group 1 Elements?

Group 1 elements of the periodic table are called Alkali Metals. They are highly reactive metals and are found in the s-block because their outermost electron enters the s-orbital.

👉 General Electronic Configuration: ns1 (where n = 2 to 7)


🌟 List of Group 1 Elements

ElementSymbolAtomic NumberPhysical StateAppearance
LithiumLi3SolidSilvery-white
SodiumNa11SolidSilvery-white
PotassiumK19SolidSilvery-grey
RubidiumRb37SolidSilvery-grey
CesiumCs55Liquid (near room temperature)Golden
FranciumFr87Liquid (radioactive)Unknown (highly unstable)

⚙️ Important Properties of Group 1 Elements

  • 💥 Highly reactive, especially with water.
  • 🌡️ Low melting and boiling points (compared to other metals).
  • ⚖️ Soft metals – can be cut with a knife.
  • 📈 Reactivity increases down the group.
  • 💧 React with water to form alkalies (strong bases) and hydrogen gas.
  • 🧪 Form colorless ionic compounds.

🔬 Reaction with Water

$$\text{2Na + 2H}_2\text{O} \rightarrow 2NaOH + H_2 \uparrow$$

This reaction produces:

  • Alkali (NaOH) – a strong base
  • Hydrogen gas – burns with a ‘pop’ sound

📌 Trends in Group 1 Elements

PropertyTrend Down the Group
Atomic RadiusIncreases
Ionization EnergyDecreases
Metallic CharacterIncreases
DensityIncreases (except K < Na)
Melting and Boiling PointsDecrease

💡 Quick Facts

  • 🟡 Cesium is a liquid near room temperature and has a golden glow.
  • ☢️ Francium is radioactive and extremely rare.
  • 🧪 All alkali metals form +1 ions (M⁺+) in reactions.
  • 🚫 Must be stored under kerosene/oil to prevent oxidation.

🧠 Do You Know?

  • 🔋 Lithium is used in rechargeable batteries.
  • 🍽️ Sodium compounds like NaCl (common salt) are essential in our diet.
  • 🚀 Potassium nitrate (KNO3) is a component in gunpowder.
  • Cesium clocks are used in atomic timekeeping.

🔷 Group 2 Elements – Alkaline Earth Metals

🧪 What Are Group 2 Elements?

Group 2 elements of the periodic table are called Alkaline Earth Metals. These elements belong to the s-block as their outermost electron enters the s-orbital, specifically with the configuration ns².

👉 General Electronic Configuration: ns2 (where n = 2 to 7)


🌟 List of Group 2 Elements

ElementSymbolAtomic NumberPhysical StateAppearance
BerylliumBe4SolidSteel-grey
MagnesiumMg12SolidSilvery-white
CalciumCa20SolidSilvery-white
StrontiumSr38SolidSilvery-grey
BariumBa56SolidSilvery-white
RadiumRa88SolidSilvery-white (Radioactive)

⚙️ Key Properties of Group 2 Elements

  • ⚗️ Less reactive than Group 1 but still reactive, especially with water and acids.
  • 🔥 Burn in air to form oxides.
  • 💧 Oxides are basic and sparingly soluble in water — hence the name alkaline.
  • 🧱 Commonly found in earth’s crust as minerals and ores.
  • ⚖️ Form divalent ions (M2+) in compounds.

🧪 Reactions of Group 2 Elements

With Water (except Be): $$\text{Ca + 2H}_2\text{O} \rightarrow \text{Ca(OH)}_2 + \text{H}_2 \uparrow$$

  • Forms alkaline hydroxides.
  • Beryllium does not react with water due to formation of a passive oxide layer.

With Oxygen: $$2Mg + O_2 \rightarrow 2MgO$$

  • Forms white metal oxides that are basic in nature.

📊 Trends in Group 2 Elements

PropertyTrend Down the Group
Atomic RadiusIncreases
Ionization EnergyDecreases
ReactivityIncreases
Melting and Boiling PointsDecrease
Solubility of HydroxidesIncreases

💡 Quick Facts

  • ⚠️ Radium (Ra) is radioactive and was once used in luminous paints.
  • 💊 Magnesium hydroxide is used as an antacid (milk of magnesia).
  • 🏗️ Calcium compounds like CaCO₃ are found in chalk, marble, and limestone.
  • 🚫 Beryllium is toxic and has covalent character in its compounds.

🧠 Do You Know?

  • 🧪 Magnesium burns with a bright white flame, used in fireworks and flares.
  • 🦴 Calcium is essential for bones and teeth in the human body.
  • 💡 Barium sulfate is used in X-ray imaging of the digestive tract.
  • 🪦 Radium was discovered by Marie Curie and is a source of radiation.

🔹 Group 1 and Group 2 Elements

  • Group 1 Elements are known as Alkali Metals.
    💧 They react with water to form alkalies (basic solutions).
  • Group 2 Elements are known as Alkaline Earth Metals.
    🌱 Their oxides also form alkalies with water and are commonly found in the earth’s crust.

📊 Key Characteristics of s-Block Elements

PropertyDescription
🧬 Electron ConfigurationEnds in ns1 or ns2
📦 Total Number14 s-block elements in total
☢️ Radioactive ElementsFrancium (Fr-87) and Radium (Ra-88)
🌬️ Gaseous ElementsHydrogen (H) and Helium (He)
💧 Liquid ElementsCesium (Cs) and Francium (Fr) are liquid at or near room temperature

💡 Quick Facts to Remember

  • 🌍 Alkaline earth metals are called so because they are found in earth’s crust and their oxides form alkalies.
  • 🌊 Alkali metals react vigorously with water.
  • 🔬 Francium and Radium are radioactive.
  • 🧊 Hydrogen and Helium are gaseous at room temperature.
  • 🧪 Cesium and Francium are liquid s-block elements.

🧠 Do You Know?

  • Francium is the most electropositive element in the periodic table.
  • Helium, though placed in group 18 due to its inert nature, electronically belongs to the s-block.
  • Cesium has a melting point of just 28.5°C, which is why it’s liquid in hot climates.

📘 Conclusion
s-Block elements are essential to understanding the periodic classification. From the lightest gas hydrogen to the radioactive Francium, they showcase a wide range of chemical and physical properties that play a vital role in modern chemistry.


Tags: s-block elements, periodic table, alkali metals, alkaline earth metals, chemistry class 11, NEET, JEE
📚 Category: Class 11 Chemistry, Periodic Classification


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⬅️ Modern Periodic Table